Department of Chemistry, University of Otago, PO Box 56, Dunedin, New Zealand.
Dalton Trans. 2010 Mar 7;39(9):2371-8. doi: 10.1039/b923211g. Epub 2010 Jan 19.
Readily synthesised mono- and di- 1,4-substituted-1,2,3-triazole "click" ligands are shown to self-assemble into discrete metallocyclic architectures with Ag(I) ions. The silver metallomacrocycles are stable in solution and the solid state and have been fully characterised by elemental analysis, HR-ESMS, IR, (1)H and (13)C NMR and in three cases the structures were confirmed by X-ray crystallography.
易于合成的单取代和二取代 1,4-取代-1,2,3-三唑“点击”配体与 Ag(I) 离子自组装成离散的金属环结构。银金属大环在溶液和固态中稳定，并通过元素分析、高分辨率电喷雾质谱 (HR-ESMS)、红外 (IR)、(1)H 和 (13)C NMR 以及在三种情况下通过 X 射线晶体学得到了充分的表征。
