State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute, Sichuan University, Chengdu 610065, China.
Bioresour Technol. 2010 Jun;101(12):4703-7. doi: 10.1016/j.biortech.2010.01.110. Epub 2010 Feb 16.
In this paper, we explored a facile method to prepare stable silver nanoparticles (Ag NPs) using extracted wool keratin as the capping agent. The formation of Ag NPs was investigated by UV-Vis spectroscopy, X-ray photo-electron spectrometer and X-ray diffraction spectrometer. The morphology of the NPs was detected by scanning electron microscopy in vacuum and atomic force microscopy in fluid. The possible interactions between the silver core and the capping agent have been investigated using Fourier transform infrared spectroscopy. The effects of keratin concentration on the incubation of the NPs were studied by UV-Vis spectra. It was found that under alkaline condition the process of incubation was much faster than that under neutral pH condition. The photoluminescence properties of the Ag NPs were also investigated. We believe that this work is helpful for the high-value utilization of wool and other keratin-rich bioresource.
在本文中,我们探索了一种简便的方法,使用提取的羊毛角蛋白作为稳定剂来制备稳定的银纳米粒子(Ag NPs)。通过紫外可见分光光度计、X 射线光电子能谱仪和 X 射线衍射仪研究了 Ag NPs 的形成。通过真空中的扫描电子显微镜和流体中的原子力显微镜检测了 NPs 的形态。通过傅里叶变换红外光谱研究了银核与稳定剂之间可能的相互作用。通过紫外可见光谱研究了角蛋白浓度对 NPs 孵化的影响。结果发现,在碱性条件下,孵化过程比在中性 pH 条件下快得多。还研究了 Ag NPs 的光致发光性质。我们相信这项工作有助于羊毛和其他富含角蛋白的生物资源的高价值利用。