Beijing National Laboratory for Molecular Science (BNLMS), State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, PR China.
Chem Commun (Camb). 2010 Mar 14;46(10):1736-8. doi: 10.1039/b924603g. Epub 2010 Feb 5.
Stoichiometric early transition metal oxide cations (TiO(2))(1-5)(+), (ZrO(2))(1-4)(+), (HfO(2))(1-2)(+), (V(2)O(5))(1-5)(+), (Nb(2)O(5))(1-3)(+), (Ta(2)O(5))(1-2)(+), (MoO(3))(1-2)(+), (WO(3))(1-3)(+), and Re(2)O(7)(+) are able to activate the C-H bond of methane under near room temperature conditions.
化学计量比的早期过渡金属氧化物阳离子（TiO(2))(1-5)(+)、(ZrO(2))(1-4)(+)、(HfO(2))(1-2)(+)、(V(2)O(5))(1-5)(+)、(Nb(2)O(5))(1-3)(+)、(Ta(2)O(5))(1-2)(+)、(MoO(3))(1-2)(+)、(WO(3))(1-3)(+)和 Re(2)O(7)(+)能够在接近室温的条件下激活甲烷的 C-H 键。
