金（I）衍生的硫代半卡巴腙配合物具有罕见的卤素-卤素相互作用-还原[Au(damp-C1,N)Cl2]。
Gold(I) derived thiosemicarbazone complexes with rare halogen-halogen interaction-reduction of [Au(damp-C1,N)Cl2].
机构信息
Department of Chemistry, University of Cape Town, Rondebosch 7701, Cape Town, South Africa.
出版信息
Dalton Trans. 2010 Mar 14;39(10):2697-700. doi: 10.1039/b925037a. Epub 2010 Jan 29.
DOI:10.1039/b925037a
PMID:20179866
Abstract
An attempt to prepare gold(III) complexes of thiosemicarbazones with the starting material gold(III) [Au(damp-C(1),N)Cl(2)] led instead to gold(I) complexes with a rare Cl...Cl interaction.
摘要
尝试用金(III) [Au(damp-C(1),N)Cl(2)]作为起始原料制备硫代半卡巴腙的金(III)配合物，结果得到的却是具有罕见 Cl…Cl 相互作用的金(I)配合物。
相似文献
1
Gold(I) derived thiosemicarbazone complexes with rare halogen-halogen interaction-reduction of [Au(damp-C1,N)Cl2].金（I）衍生的硫代半卡巴腙配合物具有罕见的卤素-卤素相互作用-还原[Au(damp-C1,N)Cl2]。
Dalton Trans. 2010 Mar 14;39(10):2697-700. doi: 10.1039/b925037a. Epub 2010 Jan 29.
2
Stable gold(III) complexes with thiosemicarbazone derivatives.与硫代氨基脲衍生物形成的稳定金（III）配合物。
Dalton Trans. 2004 Feb 21(4):677-82. doi: 10.1039/b312978k. Epub 2004 Jan 19.
3
Complexes of dichloro[2-(dimethylaminomethyl)phenyl-C1,N]gold(III), [Au(damp-C1,N)Cl2], with formylferrocene thiosemicarbazones: synthesis, structure and cytotoxicity.
J Inorg Biochem. 2004 Jun;98(6):1009-16. doi: 10.1016/j.jinorgbio.2004.02.019.
4
Gold(III) bis-thiosemicarbazonato complexes: synthesis, characterization, radiochemistry and X-ray crystal structure analysis.三价金双硫代半卡巴腙配合物的合成、表征、放射化学和 X 射线晶体结构分析。
Nucl Med Biol. 2010 Jan;37(1):41-9. doi: 10.1016/j.nucmedbio.2009.08.003. Epub 2009 Oct 3.
5
Aurophilicity in gold(I) thiosemicarbazone clusters.金（I）硫代半卡巴腙簇中的亲金性。
Dalton Trans. 2012 Jan 28;41(4):1363-72. doi: 10.1039/c1dt11680k. Epub 2011 Nov 24.
6
Stabilization of gold(I) and gold(III) complexes by pyridil bis{3-hexamethylene-iminylthiosemicarbazone}: spectroscopic, structural and computational study.吡啶基双{3-六亚甲基-亚氨基硫代半卡巴腙}对金（I）和金（III）配合物的稳定作用：光谱、结构和计算研究
Dalton Trans. 2009 Apr 21(15):2731-9. doi: 10.1039/b811897c. Epub 2009 Feb 20.
7
Halogen photoreductive elimination from metal-metal bonded iridium(II)-gold(II) heterobimetallic complexes.卤原子光还原消除金属键合的铱（II）-金（II）杂双金属配合物。
Inorg Chem. 2010 Mar 15;49(6):3035-43. doi: 10.1021/ic902590u.
8
Rhodium assisted C-H activation of benzaldehyde thiosemicarbazones and their oxidation via activation of molecular oxygen.
Inorg Chem. 2006 Feb 6;45(3):1252-9. doi: 10.1021/ic050505w.
9
Synthesis and in vitro evaluation of gold(I) thiosemicarbazone complexes for antimalarial activity.合成及体外评价金（I）硫代半卡巴腙类化合物的抗疟活性。
J Inorg Biochem. 2010 Oct;104(10):1079-83. doi: 10.1016/j.jinorgbio.2010.06.005. Epub 2010 Jul 1.
10
Pyridine-derived thiosemicarbazones and their tin(IV) complexes with antifungal activity against Candida spp.吡啶衍生的硫代缩氨基脲及其锡(IV)配合物对念珠菌属的抗真菌活性
Eur J Med Chem. 2011 May;46(5):1473-82. doi: 10.1016/j.ejmech.2011.01.041. Epub 2011 Feb 25.
Zotero 插件