• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

压力诱导的 Mn12 纳米磁体中的 Jahn-Teller 转变。

Pressure-induced Jahn-Teller switching in a Mn12 nanomagnet.

机构信息

WestCHEM, Department of Chemistry, University of Glasgow, University Avenue, Glasgow, UK G12 8QQ.

出版信息

Chem Commun (Camb). 2010 Mar 21;46(11):1881-3. doi: 10.1039/b923962f. Epub 2010 Jan 18.

DOI:10.1039/b923962f
PMID:20198240
Abstract

Pressure-induced switching of a fast-relaxing single-molecule magnet to a slow-relaxing isomer is observed for the first time by using a combination of high pressure single-crystal X-ray diffraction and high pressure magnetic measurements.

摘要

首次通过高压单晶 X 射线衍射和高压磁测量相结合的方法，观察到压力诱导快速弛豫单分子磁体向缓慢弛豫异构体的转变。

相似文献

1
Pressure-induced Jahn-Teller switching in a Mn12 nanomagnet.压力诱导的 Mn12 纳米磁体中的 Jahn-Teller 转变。
Chem Commun (Camb). 2010 Mar 21;46(11):1881-3. doi: 10.1039/b923962f. Epub 2010 Jan 18.
2
Observation of a secondary slow relaxation process for the field-induced single-molecule magnet U(H2BPz2)3.观测到场诱导单分子磁体 U(H2BPz2)3 的二级慢弛豫过程。
J Am Chem Soc. 2010 Jun 9;132(22):7572-3. doi: 10.1021/ja1009019.
3
High pressure induced spin changes and magneto-structural correlations in hexametallic SMMs.
Dalton Trans. 2009 Jul 7(25):4858-67. doi: 10.1039/b902485a. Epub 2009 May 7.
4
Structural basis for the phase switching of bisaminecopper(II) cations at the thermal limits of lattice stability.双胺铜（II）阳离子在晶格稳定性热极限处发生相转变的结构基础。
Inorg Chem. 2006 Jun 26;45(13):5027-33. doi: 10.1021/ic060110s.
5
[Mn12O12(OMe)2(O2CPh)16(H2O)2]2- single-molecule magnets and other manganese compounds from a reductive aggregation procedure.通过还原聚集法制备的[Mn12O12(OMe)2(O2CPh)16(H2O)2]2-单分子磁体及其他锰化合物。
Inorg Chem. 2005 Sep 5;44(18):6324-38. doi: 10.1021/ic050868w.
6
A two-dimensional iron(II) carboxylate linear chain polymer that exhibits a metamagnetic spin-canted antiferromagnetic to single-chain magnetic transition.一种二维羧酸铁（II）线性链聚合物，其表现出从变磁自旋倾斜反铁磁到单链磁转变。
Inorg Chem. 2008 May 19;47(10):4077-87. doi: 10.1021/ic701879y. Epub 2008 Apr 19.
7
Single-molecule-magnet behavior and spin changes affected by crystal packing effects.单分子磁体行为以及受晶体堆积效应影响的自旋变化。
Inorg Chem. 2008 Oct 6;47(19):8610-2. doi: 10.1021/ic801208z. Epub 2008 Sep 5.
8
Three-Dimensional (3-D) Ferromagnetic Network of Mn Single-Molecule Magnets: Subtle Environmental Effects and Switching to Antiferromagnetic.锰单分子磁体的三维（3-D）铁磁网络：微妙的环境效应与向反铁磁的转变
Inorg Chem. 2017 Sep 5;56(17):10706-10716. doi: 10.1021/acs.inorgchem.7b01676. Epub 2017 Aug 22.
9
DFT-based studies on the Jahn-Teller effect in 3d hexacyanometalates with orbitally degenerate ground states.基于密度泛函理论（DFT）对具有轨道简并基态的3d六氰基金属配合物中 Jahn-Teller 效应的研究。
J Phys Chem A. 2007 Sep 20;111(37):9145-63. doi: 10.1021/jp0731912. Epub 2007 Aug 24.
10
The dynamic Jahn-Teller effect in Cu(II) doped MgO.Cu(II) 掺杂MgO中的动态 Jahn-Teller 效应
J Chem Phys. 2009 Mar 14;130(10):104708. doi: 10.1063/1.3086038.

引用本文的文献

1
The pressure response of Jahn-Teller-distorted Prussian blue analogues.Jahn-Teller 畸变普鲁士蓝类似物的压力响应
Chem Sci. 2024 Jan 23;15(9):3155-3164. doi: 10.1039/d3sc06912e. eCollection 2024 Feb 28.
2
The curious case of proton migration under pressure in the malonic acid and 4,4'-bipyridine cocrystal.丙二酸与4,4'-联吡啶共晶中质子在压力下迁移的奇特现象。
IUCrJ. 2024 Mar 1;11(Pt 2):168-181. doi: 10.1107/S2052252524000344.
3
Pressure-induced Jahn-Teller switch in the homoleptic hybrid perovskite [(CH)NH]Cu(HCOO): orbital reordering by unconventional degrees of freedom.
压力诱导的纯配体杂化钙钛矿[(CH)NH]Cu(HCOO)中的 Jahn-Teller 转变：通过非常规自由度实现的轨道重排
J Mater Chem C Mater. 2021 Jun 9;9(25):8051-8056. doi: 10.1039/d1tc01966j. eCollection 2021 Jul 1.
4
Pressure-and temperature induced phase transitions, piezochromism, NLC behaviour and pressure controlled Jahn-Teller switching in a Cu-based framework.基于铜的框架中的压力和温度诱导相变、压致变色、向列相液晶行为以及压力控制的 Jahn-Teller 开关效应
Chem Sci. 2020 Jul 30;11(33):8793-8799. doi: 10.1039/d0sc03229h.
5
Magnetic Behaviour of Mn-Stearate Single-Molecule Magnets Immobilized on the Surface of 300 nm Spherical Silica Nanoparticles.固定在300纳米球形二氧化硅纳米颗粒表面的硬脂酸锰单分子磁体的磁行为
Materials (Basel). 2020 Jun 9;13(11):2624. doi: 10.3390/ma13112624.
6
Molecular multifunctionality preservation upon surface deposition for a chiral single-molecule magnet.手性单分子磁体表面沉积后分子多功能性的保留
Chem Sci. 2019 Jan 24;10(10):3065-3073. doi: 10.1039/c8sc04917c. eCollection 2019 Mar 14.
7
Studying weak inter-actions in crystals at high pressures: when hardware matters.在高压下研究晶体中的弱相互作用：硬件的重要性。
Acta Crystallogr E Crystallogr Commun. 2018 Apr 17;74(Pt 5):613-619. doi: 10.1107/S205698901800470X. eCollection 2018 May 1.
8
Probing the origin of the giant magnetic anisotropy in trigonal bipyramidal Ni(ii) under high pressure.高压下三角双锥镍（II）中巨磁各向异性起源的探究
Chem Sci. 2017 Dec 19;9(6):1551-1559. doi: 10.1039/c7sc04460g. eCollection 2018 Feb 14.
9
Observation of a re-entrant phase transition in the molecular complex tris(μ-3,5-diiso-propyl-1,2,4-triazolato-κ:)trigold(I) under high pressure.高压下分子配合物三（μ-3,5-二异丙基-1,2,4-三唑基-κ:）三（金（I））中再入式相变的观察
IUCrJ. 2016 Aug 18;3(Pt 5):367-376. doi: 10.1107/S2052252516013129. eCollection 2016 Sep 1.
10
Dynamic molecular crystals with switchable physical properties.具有可切换物理性质的动态分子晶体。
Nat Chem. 2016 Jun 21;8(7):644-56. doi: 10.1038/nchem.2547.