School of Chemistry, University of St Andrews, North Haugh, St Andrews, Fife, Scotland, UK KY16 9ST.
Dalton Trans. 2010 Mar 21;39(11):2751-64. doi: 10.1039/b913778e. Epub 2010 Jan 4.
The development of catalytic chemical conversions owes its success to the procreation of ligand variety and parameter quantification. Rational ligand design can provide a powerful means to tune transition metal reactivity and reaction selectivity. In this review an attempt is made to describe the quantification of ligand parameters and to present examples of successful ligand design in several academically and industrially important catalytic systems.
催化化学反应的发展归功于配体多样性和参数量化的产生。合理的配体设计可以为调节过渡金属反应性和反应选择性提供有力手段。在这篇综述中，我们尝试描述配体参数的量化，并介绍几个在学术和工业上重要的催化体系中成功的配体设计实例。
