Department of Chemistry, CICECO or CESAM, University of Aveiro, 3810-193 Aveiro, Portugal.
J Colloid Interface Sci. 2010 May 15;345(2):234-40. doi: 10.1016/j.jcis.2010.01.087. Epub 2010 Feb 6.
The magnetic removal of Hg(2+) from water has been assessed using silica coated magnetite particles. The magnetite particles were first prepared by hydrolysis of FeSO(4) and their surfaces were modified with amorphous silica shells that were then functionalized with organic moieties containing terminal dithiocarbamate groups. Under the experimental conditions used, the materials reported here displayed high efficiency for Hg(2+) uptake (74%) even at contaminant levels as low as 50 μg l(-1). Therefore these eco-nanomagnets show great potential for the removal of heavy metal ions of polluted water, via magnetic separation.
采用二氧化硅包覆的磁铁矿颗粒评估了从水中去除汞离子(Hg(2+))的效果。首先通过硫酸亚铁(FeSO(4))的水解制备了磁铁矿颗粒,并在其表面修饰了无定形二氧化硅壳,然后将其功能化,接上含有末端二硫代氨基甲酸盐基团的有机基团。在所使用的实验条件下,即使在污染物水平低至 50μg l(-1) 的情况下,这里报道的材料对 Hg(2+)的去除效率也很高(74%)。因此,这些环保纳米磁体在通过磁分离去除受污染水中的重金属离子方面具有很大的潜力。