轴向手性氨基酸衍生物在中断结晶过程中的自发对称破缺。
Spontaneous symmetry breaking during interrupted crystallization of an axially chiral amino acid derivative.
机构信息
Department of Chemistry, Oregon State University, Corvallis, Oregon 97331-4003, USA.
出版信息
Chem Commun (Camb). 2010 Mar 28;46(12):2094-6. doi: 10.1039/b922028c. Epub 2010 Feb 19.
DOI:10.1039/b922028c
PMID:20221503
Abstract
High net enantiomeric excess was observed for crystal collections obtained by crystallization of the TFA salt of a configurationally stable yet racemic axially chiral amidoamine in EtOH solution with or without stirring (up to >99% ee at < or = 15% crystallization).
摘要
高对映体过量的晶体是通过在 EtOH 溶液中对构型稳定但外消旋的轴手性酰胺叔丁基亚磺酸盐进行结晶，无论是搅拌还是不搅拌（在结晶度达到 15%以下时，ee 值高达>99%）。
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