ETSF Scientific Development Centre, Departamento Fisica de Materiales, Universidad del Pais Vasco, San Sebastian, Spain.
Nano Lett. 2010 Apr 14;10(4):1172-6. doi: 10.1021/nl9034626.
We present a new way to tune the electron-phonon coupling (EPC) in graphene by changing the deformation potential with electron/hole doping. We show the EPC for highest optical branch at the high symmetry point K acquires a strong dependency on the doping level due to electron-electron correlation not accounted in mean-field approaches. Such a dependency influences the dispersion (with respect to the laser energy) of the Raman D and 2D lines and the splitting of the 2D peak in multilayer graphene. Finally this doping dependence opens the possibility to construct tunable electronic devices through external control of the EPC.
我们提出了一种通过电子/空穴掺杂改变变形势来调节石墨烯中电子-声子耦合(EPC)的新方法。我们表明,由于平均场方法未考虑电子-电子相关,高对称点 K 处的最高光学支 EPC 强烈依赖于掺杂水平。这种依赖性会影响拉曼 D 和 2D 线的色散(相对于激光能量)以及多层石墨烯中 2D 峰的劈裂。最后,这种掺杂依赖性为通过外部控制 EPC 来构建可调谐电子器件提供了可能性。