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Superspace description of the homologous series Ga2O3(ZnO)m.

作者信息

Michiue Yuichi, Kimizuka Noboru

机构信息

National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan.

出版信息

Acta Crystallogr B. 2010 Apr;66(Pt 2):117-29. doi: 10.1107/S0108768109053713. Epub 2010 Feb 26.

DOI:10.1107/S0108768109053713
PMID:20305345
Abstract

A unified description for the structures of the homologous series Ga(2)O(3)(ZnO)(m), gallium zinc oxide, is presented using the superspace formalism. The structures were treated as a compositely modulated structure consisting of two subsystems. One is constructed with metal ions and the other with O ions. The ideal model is given, in which the displacive modulations of ions are well described by the zigzag function with large amplitudes. Alternative settings are also proposed which are analogous to the so-called modular structures. The validity of the model has been confirmed by refinements for phases with m = 6 and m = 9 in the homologous series. A few complex phenomena in real structures are taken into account by modifying the ideal model.

摘要

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