Department of Chemistry, National University of Singapore, Singapore.
Angew Chem Int Ed Engl. 2010 Apr 6;49(16):2888-92. doi: 10.1002/anie.200906783. Epub 2010 Mar 19.
Sowing the seeds: the growth of Au and Ag(2)S nanoparticles at distinct positions on CdSe-seeded CdS heterostructured nanorods can be precisely controlled by variations in the concentration of the Au and Ag precursors, respectively. The ability to direct growth on the nanorods can lead to "Janus-type" structures where Au is located at the more reactive end of the nanorod, whilst Ag(2)S is located at the other (see picture; CdSe dark blue, CdS light blue, Au yellow, Ag(2)S gray).
通过改变 Au 和 Ag 前体的浓度,可以精确控制 Au 和 Ag(2)S 纳米粒子分别在 CdSe 种子 CdS 异质结构纳米棒的不同位置生长。在纳米棒上定向生长的能力可以导致“双面型”结构,其中 Au 位于纳米棒更活跃的一端,而 Ag(2)S 位于另一端(见图片;CdSe 深蓝色,CdS 浅蓝色,Au 黄色,Ag(2)S 灰色)。