School of Chemistry, University of Edinburgh, King's Buildings, West Mains Road, Edinburgh, UK EH9 3JJ.
Chem Commun (Camb). 2010 Apr 14;46(14):2382-4. doi: 10.1039/c001697g. Epub 2010 Mar 5.
A second generation palladium(II)-complexed molecular shuttle, featuring structural changes to the size and shape of the macrocycle, shows significantly increased rates of shuttling and improved co-conformational bias compared to the original system.
第二代钯(II)配合的分子梭,其大环的尺寸和形状发生了结构变化,与原始系统相比,其穿梭速度显著提高,共构构象偏向性也得到改善。