CAS Key Laboratory of Organic Solids, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry Chinese Academy of Sciences, Beijing 100190, People's Republic of China.
Luminescence. 2011 May-Jun;26(3):185-90. doi: 10.1002/bio.1204. Epub 2010 Mar 22.
Two novel cyano-containing oligo(phenylenevinylene) (OPV) derivatives have been designed and synthesized. Photophysical and sensing properties of the two compounds were studied. Such studies reveal the intramolecular charge transfer process between cyano groups and OPV core. The results showed that the alkyl difference of substituted OPV leads to the changes of molecular configuration and metallo-response of two compounds.
两种新型含氰基的寡聚（苯并二呋喃乙烯）（OPV）衍生物被设计并合成。对这两种化合物的光物理和传感性能进行了研究。这些研究揭示了氰基基团和 OPV 核心之间的分子内电荷转移过程。结果表明，取代的 OPV 的烷基差异导致了两种化合物的分子构象和金属响应的变化。
