Department of Chemistry and Center of Novel Functional Molecules, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong SAR, People's Republic of China.
Inorg Chem. 2010 Apr 19;49(8):3676-8. doi: 10.1021/ic901697f.
Three polyoxometalate-based silver(I) ethynediide complexes have been obtained by hydrothermal synthesis. New types of polyoxometalate motifs are generated and stabilized in a silver-rich environment in their respective three-dimensional coordination frameworks via assembly of the polyhedral metal-ligand C(2)@Ag(n) (n = 6 and 7) supramolecular synthon.
通过水热合成得到了三种基于多金属氧酸盐的银（I）乙炔二化物配合物。在富含银的环境中，通过多面体金属-配体 C(2)@Ag(n)（n = 6 和 7）超分子合成子的组装，在各自的三维配位框架中生成并稳定了新型的多金属氧酸盐基元。
