INFIQC, Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, Ciudad Universitaria, Argentina.
Org Lett. 2010 Apr 16;12(8):1884-7. doi: 10.1021/ol100520m.
Cycloreversion (CR) of thietane radical cations leads to formation of thiobenzophenone and the corresponding alkenes, eventually followed by secondary [4 + 2] cycloaddition. Final product distribution depends on the ability of fragments to escape from ion-molecule complexes (IMCs).
硫杂环丁烷自由基阳离子的环反转 (CR) 导致硫代苯甲酮和相应的烯烃的形成，最终随后是次级 [4 + 2] 环加成。最终产物分布取决于碎片从离子-分子复合物 (IMC) 中逃逸的能力。
