Klein W, Weisgerber I
Environ Qual Saf. 1976;5:237-50.
A survey is given on reported PCB-residues and accumulation in various environmental media including water and aquatic environment, flora, animals, food, and humans. Model studies with technical PCB, as well as with pure individual components, are presented from various working groups. As examples, metabolic studies and photochemical experiments are discussed. According to our present knowledge, a major metabolic pathway in animals and plants is hydroxylation, often followed by methylation or conjugation. By UV-irradiation, however, oxygenation, dechlorination and chlorination, polymerization and isomerization may occur.
本文综述了多氯联苯(PCB)在包括水和水生环境、植物、动物、食物及人类在内的各种环境介质中的残留及累积情况。不同工作组展示了使用工业多氯联苯以及纯单一成分进行的模型研究。文中以代谢研究和光化学实验为例展开讨论。根据我们目前的认知,动植物体内主要的代谢途径是羟基化,随后常伴随甲基化或结合反应。然而,通过紫外线照射,可能会发生氧化、脱氯和氯化、聚合及异构化反应。