Physical and Materials Chemistry Division, National Chemical Laboratory, Dr. Homi Bhabha Road, Pashan, Pune 411 008, India.
ACS Appl Mater Interfaces. 2009 Sep;1(9):2030-5. doi: 10.1021/am900396m.
A 50% enhancement in the conversion efficiency (4.9-7.37%) is realized in dye-sensitized solar cells using hydrothermally synthesized TiO(2)-multiwalled carbon nanotube (MWCNT) nanocomposites as compared to hydrothermally synthesized TiO(2) without MWCNT and Degussa P25. Several characterizations have been employed to reveal the nature of the modification imparted to the MWCNTs under hydrothermal processing conditions and the resulting TiO(2)-MWCNT conjugation through -COOH groups. Efficient charge transfer in the nanocomposite and efficient electron transport by MWCNT (significantly higher incident-photon-to-current conversion efficiency) are suggested to be the possible reasons for the enhancement.
与未添加多壁碳纳米管(MWCNT)的水热合成 TiO 2 和 Degussa P25 相比,水热合成的 TiO 2-MWCNT 纳米复合材料可将染料敏化太阳能电池的能量转换效率提高 50%(4.9-7.37%)。采用多种表征手段揭示了 MWCNT 在水热条件下修饰的本质,以及通过 -COOH 基团实现的 TiO 2-MWCNT 结合。MWCNT 可实现纳米复合材料中的高效电荷转移和电子传输(显著提高了光电流转换效率),这可能是性能提升的原因。