金纳米棒间隙结构对表面增强拉曼散射强度的影响。
Gap structure effects on surface-enhanced Raman scattering intensities for gold gapped rods.
机构信息
Department of Chemistry, Northwestern University, Evanston, Illinois 60208, USA.
出版信息
Nano Lett. 2010 May 12;10(5):1722-7. doi: 10.1021/nl100099g.
Gapped rods provide a unique platform for elucidating structure/function relationships, both for single-molecule electrochemical techniques and for surface-enhanced Raman scattering (SERS). This paper attempts to elucidate the dependence of SERS intensities on gap topography and gap distance for gold gapped rods with segment lengths varying over a wide range (40-2000 nm). Significantly, we have determined that rough gaps lead to a smaller SERS enhancement than smooth gaps for these structures even though the rough gaps have a larger total surface area. Both theory and experiment show periodic variation of SERS intensity with segment length as determined by odd-symmetry plasmon multipoles. Excitation of even-symmetry modes is dipole forbidden (for polarization along the rod axis), but this selection rule can be relaxed by roughness or, for smooth gaps, by near-field coupling between the rod segments.
缺口棒为阐明结构/功能关系提供了一个独特的平台,无论是对于单分子电化学技术还是对于表面增强拉曼散射(SERS)都是如此。本文试图阐明金缺口棒的 SERS 强度对间隙形貌和间隙距离的依赖性,这些金缺口棒的段长范围很广(40-2000nm)。重要的是,我们已经确定,对于这些结构,即使粗糙的间隙具有更大的总表面积,粗糙的间隙也会导致比光滑的间隙更小的 SERS 增强。理论和实验都表明,SERS 强度随段长的周期性变化由奇数对称等离子体多极决定。对于沿棒轴的极化,偶数对称模式的激发是偶极子禁止的,但这种选择定则可以通过粗糙度或对于光滑的间隙,通过棒段之间的近场耦合来放宽。