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耦合金纳米球/纳米盘三聚体的声等离子体和表面增强拉曼散射特性。

Acousto-plasmonic and surface-enhanced Raman scattering properties of coupled gold nanospheres/nanodisk trimers.

机构信息

Institute of Material Research and Engineering, A*STAR, Singapore.

出版信息

Nano Lett. 2011 Feb 9;11(2):431-7. doi: 10.1021/nl103089e. Epub 2011 Jan 7.

Abstract

This work is devoted to the fundamental understanding of the interaction between acoustic vibrations and surface plasmons in metallic nano-objects. The acoustoplasmonic properties of coupled spherical gold nanoparticles and nanodisk trimers are investigated experimentally by optical transmission measurements and resonant Raman scattering experiments. For excitation close to resonance with the localized surface plasmons of the nanodisk trimers, we are able to detect several intense Raman bands generated by the spherical gold nanoparticles. On the basis of both vibrational dynamics calculations and Raman selection rules, the measured Raman bands are assigned to fundamental and overtones of the quadrupolar and breathing vibration modes of the spherical gold nanoparticles. Simulations of the electric near-field intensity maps performed at the Raman probe wavelengths showed strong localization of the optical energy in the vicinity of the nanodisk trimers, thus corroborating the role of the interaction between the acoustic vibrations of the spherical nanoparticles and the surface plasmons of the nanodisk trimers. Acoustic phonons surface enhanced Raman scattering is here demonstrated for the first time for such coupled plasmonic systems. This work paves the way to surface plasmon engineering for sensing the vibrational properties of nanoparticles.

摘要

这项工作致力于深入理解声学振动与金属纳米物体中表面等离激元之间的相互作用。我们通过光学透射测量和共振拉曼散射实验实验性地研究了耦合金球纳米粒子和纳米盘三聚体的声等离子体特性。对于接近纳米盘三聚体局域表面等离激元共振的激发,我们能够检测到由金球纳米粒子产生的几个强烈的拉曼带。基于振动动力学计算和拉曼选择定则,测量的拉曼带被分配到金球纳米粒子的四极和呼吸振动模式的基频和泛频。在拉曼探针波长处进行的近场强度图谱模拟显示,光学能量在纳米盘三聚体附近强烈局域化,从而证实了金球纳米粒子的声振动与纳米盘三聚体的表面等离激元之间相互作用的作用。首次在此类耦合等离子体系统中展示了声子表面增强拉曼散射。这项工作为用于感测纳米粒子振动特性的表面等离激元工程铺平了道路。

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