在甲烯霉素呋喃生物合成中，通过立体特异性掺入 13C 标记的甘油，暗示存在一种丁烯内酯中间体。
A butenolide intermediate in methylenomycin furan biosynthesis is implied by incorporation of stereospecifically 13C-labelled glycerols.
机构信息
Department of Chemistry, University of Warwick, Coventry, CV4 7AL, UK.
出版信息
Chem Commun (Camb). 2010 Jun 21;46(23):4079-81. doi: 10.1039/c000496k. Epub 2010 Apr 1.
DOI:10.1039/c000496k
PMID:20358097
Abstract
The label from [3-(13)C]-L-glycerol is incorporated into the hydroxymethyl group of methylenomycin furans suggesting a butenolide intermediate in their biosynthesis.
摘要
[3-(13)C]-L-甘油的标签被掺入到亚甲基霉素呋喃的羟甲基中，表明它们生物合成中有丁烯内酯中间体。
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