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由弯曲核分子形成的流体纤维束。

Bundles of fluid fibers formed by bent-core molecules.

作者信息

Bailey C, Murphy M, Eremin A, Weissflog W, Jákli A

机构信息

Chemical Physics Interdisciplinary Program and Liquid Crystal Institute, Kent State University, Kent, Ohio 44242, USA.

出版信息

Phys Rev E Stat Nonlin Soft Matter Phys. 2010 Mar;81(3 Pt 1):031708. doi: 10.1103/PhysRevE.81.031708. Epub 2010 Mar 22.

Abstract

The internal structures, stability, and elastic properties of free-standing filament bundles of bent-core smectic liquid crystals are studied using polarizing microscopy, scanning electron microscopy, and a customized cantilever containing, temperature controlled heat stage for force measurements. We find that in bundles, the individual filaments fuse together to form semiseparable filaments with radii approximately two and three times larger than the individual fibers. We also find that the effective surface tension of wide bundles is about 10% smaller than a single filament. Finally, we describe the metastable coexistences of single fibers within the bundles that lead to bending of the bundles. All of these observations were explained with simple macroscopic models.

摘要

利用偏光显微镜、扫描电子显微镜以及一个定制的包含用于力测量的温度可控加热台的悬臂,研究了弯曲核近晶型液晶的独立长丝束的内部结构、稳定性和弹性特性。我们发现,在束中,单根长丝融合在一起形成半径约为单根纤维两到三倍的半可分离长丝。我们还发现,宽束的有效表面张力比单根长丝小约10%。最后,我们描述了束内单根纤维的亚稳共存,这导致了束的弯曲。所有这些观察结果都用简单的宏观模型进行了解释。

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