Laboratoire des Colloïdes, Verres et Nanomatériaux, UMR 5587 CNRS Université Montpellier II, F-34095 Montpellier Cedex 5, France.
Phys Rev Lett. 2010 Feb 12;104(6):067402. doi: 10.1103/PhysRevLett.104.067402. Epub 2010 Feb 11.
The position and strength of the boson peak in silica glass vary considerably with temperature T. Such variations cannot be explained solely with changes in the Debye energy. New Brillouin-scattering measurements are presented which allow determining the T dependence of unrelaxed acoustic velocities. Using a velocity based on the bulk modulus, scaling exponents are found which agree with the soft-potential model. The unrelaxed bulk modulus thus appears to be a good measure for the structural evolution of silica with T and to set the energy scale for the soft potentials.
二氧化硅玻璃中声子峰的位置和强度随温度 T 变化很大。这种变化不能仅用德拜能的变化来解释。本文提出了新的布里渊散射测量,这些测量可以确定非弛豫声速随 T 的变化关系。使用基于体弹性模量的速度,发现了与软势模型一致的标度指数。因此,非弛豫体弹性模量似乎是一个很好的衡量标准,可用于衡量二氧化硅随温度的结构演变,并为软势设置能量标度。