European Synchrotron Radiation Facility, BP220, F-38043 Grenoble, France.
J Chem Phys. 2010 Jul 28;133(4):041101. doi: 10.1063/1.3460815.
The results of a combined experimental study of the high-frequency acoustic dynamics and of the vibrational density of states (VDOS) as a function of temperature in a glass of sorbitol are reported here. The excess in the VDOS at approximately 4.5 meV over the Debye, elastic continuum prediction (boson peak) is found to be clearly related to anomalies observed in the acoustic dispersion curve in the mesoscopic wavenumber range of few nm(-1). The quasiharmonic temperature dependence of the acoustic dispersion curves offers a natural explanation for the observed scaling of the boson peak with the elastic medium properties.
本文报道了在山梨糖醇玻璃中高频声动力学和振动态密度(VDOS)随温度变化的联合实验研究结果。在大约 4.5 meV 处,VDOS 超过德拜弹性连续体预测(玻色峰)的部分被发现与在介观波数范围内(几个 nm(-1))的声色散曲线中观察到的异常明显相关。声色散曲线的准谐温度依赖性为观察到的玻色峰与弹性介质性质的标度提供了自然的解释。