Laboratory of Electrocatalysis, UMR-CNRS 6503, University of Poitiers, 40 Av. Recteur Pineau, 86022 Poitiers Cedex, France.
Chemphyschem. 2010 Sep 10;11(13):2732-44. doi: 10.1002/cphc.200900817.
Herein, some chemical approaches to the tailoring of nanodivided materials are highlighted. Transition-metal materials in nanodivided form are essentially devoted to study the electrocatalytic reduction of molecular oxygen (ORR) in acid medium. This Minireview focuses on the physical and chemical structures of platinum-based and non-platinum-based materials. Due to the research dynamism in this field, the discussion is limited to a comprehensive review of ORR cathode materials investigated in the author's laboratory as well as to some relevant work obtained in other laboratories concerning the electrochemical ORR pathway and substrate effects.
本文重点介绍了一些化学方法来调整纳米分散材料。纳米分散形式的过渡金属材料主要用于研究酸性介质中分子氧（ORR）的电催化还原。本综述重点介绍了基于铂和非铂的材料的物理和化学结构。由于该领域的研究动态，讨论仅限于对作者实验室研究的 ORR 阴极材料以及其他实验室获得的一些关于电化学 ORR 途径和底物效应的相关工作进行综合回顾。
