具有 1,3,2-苯并二氮杂硼杂环戊烷壁的间苯二酚空腔主体作为铵阳离子的荧光受体。
Resorcin[4]arene cavitand with 1,3,2-benzodiazaborolyl walls as a fluorescence receptor for ammonium cations.
机构信息
Department of Applied Chemistry, Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University, 1-1 Minami-ohsawa, Hachioji, Tokyo 192-0397, Japan.
出版信息
Chem Commun (Camb). 2010 May 28;46(20):3604-6. doi: 10.1039/c0cc00259c. Epub 2010 Apr 9.
PMID:20383396
Abstract
Resorcin[4]arene cavitand 1 with 1,3,2-benzodiazaborolyl walls was newly synthesized. It showed a large blue shift in the fluorescence spectra upon selective complexation with alkyltrimethylammonium salts in CH(2)Cl(2)-DMSO (9 : 1 v/v); this shift was detectable with the naked eye.
摘要
新型合成的[4]杯芳烃主体分子 1 具有 1,3,2-苯并二氮杂硼杂环戊烷壁，在与正烷基三甲基铵盐在 CH(2)Cl(2)-DMSO(9:1 v/v)选择性络合时，其荧光光谱发生了很大的蓝移；这种蓝移可用肉眼检测到。
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