基于间苯二酚[4]芳烃的苯甲酰胺亚氨基环糊精的多功能自组装分子胶囊的形成。
Versatile self-assembled molecular capsule formation of a resorcin[4]arene-based benzamidoiminocavitand.
机构信息
Department of Chemistry, Soongsil University, Seoul 156-743, Korea.
出版信息
Chem Commun (Camb). 2013 Jul 18;49(56):6316-8. doi: 10.1039/c3cc42671h.
PMID:23739461
Abstract
The facile synthesis of a resorcin[4]arene-based imino-cavitand with benzamido moieties and its self-assembly into molecular capsules are reported. Benzamido-iminocavitand efficiently self-assembled into thermally inert molecular capsules in the presence of suitable guests via the eight intermolecular N-H···O=C hydrogen bonds.
摘要
报道了一种基于间苯二酚的席夫碱型脒基环芳烃及其自组装形成分子胶囊的简便合成方法。在合适客体的存在下，苯甲酰胺亚胺环芳烃通过 8 个分子间的 N-H···O=C 氢键有效地自组装成热稳定的分子胶囊。
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