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[深红色发射新型聚合物的合成与发光特性研究]

[Research on the synthesis and luminescence characterization of deepen red emission novel polymer].

作者信息

Cheng Zhi-Ming, Xu Zheng, Fu Qiang, Zhao Su-Ling, Zhang Fu-Jun

机构信息

Key Laboratory of Luminescence and Optical Information, Beijing Jiaotong University, Ministry of Education, Beijing 100044, China.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2010 Feb;30(2):301-3.

Abstract

A deep red emission polymer (PPV-Q) was synthesized successfully. The photoluminescence, electroluminescence and absorption performance of this polymer were studied in detail. The experimental results show that the polymer has strong absorption in the ultraviolet and blue emission wavelength region. The effective excitation wavelength is about 463 nm. The organic emitting diodes based on the polymer as the active layer were prepared with the device structure: ITO/PPV-Q/Al. The electroluminescence of these devices was obtained and the peak emission wavelength is about 670 nm; the electroluminescence spectra have the full width at half maximum of about 90 nm. The CIE coordinate remains constant at (x = 0.67, y = 0.32) without change with the increase in driving voltage. The electroluminescence of this device (ITO/PPV-Q/Al) shows deep red emission. However, the current increases with the increase in driving voltage.

摘要

成功合成了一种深红色发射聚合物(PPV-Q)。详细研究了该聚合物的光致发光、电致发光和吸收性能。实验结果表明,该聚合物在紫外光和蓝光发射波长区域有较强吸收。有效激发波长约为463nm。以该聚合物为活性层制备了器件结构为ITO/PPV-Q/Al的有机发光二极管。获得了这些器件的电致发光,其峰值发射波长约为670nm;电致发光光谱的半高宽约为90nm。CIE坐标在(x = 0.67,y = 0.32)处保持不变,不随驱动电压的增加而变化。该器件(ITO/PPV-Q/Al)的电致发光呈现深红色发射。然而,电流随驱动电压的增加而增大。

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