Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371.
J Am Chem Soc. 2010 May 12;132(18):6284-5. doi: 10.1021/ja100716x.
This paper describes a palladium-catalyzed oxime assisted intramolecular dioxygenation of alkenes by using 1 atm of air as the sole oxidant under extremely mild conditions, which demonstrated the feasibility of incorporating atmospheric oxygen into synthetically useful products under 1 atm of air at room temperature.
本文描述了一种钯催化的肟辅助的烯烃的分子内双氧化反应，在极其温和的条件下仅使用 1 个大气压的空气作为唯一的氧化剂，这证明了在 1 个大气压的空气和室温下将大气中的氧气结合到合成有用产物中的可行性。
