扫描电子显微镜和固体废弃物填埋场渗滤液中氧化铁的磁性特征。

Scanning electron microscopy and magnetic characterization of iron oxides in solid waste landfill leachate.

机构信息

Faculty of Teaching and Educational Sciences, Pattimura University, Ambon 97233, Indonesia.

出版信息

J Hazard Mater. 2010 Jul 15;179(1-3):701-8. doi: 10.1016/j.jhazmat.2010.03.058. Epub 2010 Mar 19.

Abstract

Leachate sludge samples were taken from two municipal solid waste sites of Jelekong and Sarimukti in Bandung, Indonesia. Their magnetic mineralogy and granulometry were analyzed to discriminate the sources of magnetic minerals using X-ray diffraction (XRD), scanning electron microscopy equipped with energy-dispersive X-ray spectroscopy (SEM-EDX) and rock magnetism. SEM-EDX analyses infer that the main magnetic minerals in the leachate sludge are iron oxides. In terms of their morphology, the grains from Jelekong are mostly octahedral and angular, which are similar to the general shapes of magnetic grains from the local soils. The grains from Sarimukti, on the other hand, are dominated by imperfect spherule shapes suggesting the product of combustion processes. Hysteresis parameters verify that the predominant magnetic mineral in leachate sludge is low coercivity ferrimagnetic mineral such as magnetite (Fe(3)O(4)). Furthermore, comparisons of rock magnetic parameters show that the magnetic minerals of soil samples from Jelekong have higher degree of magnetic pedogenesis indicating higher proportion of superparamagnetic/ultrafine particles than those of soil samples from Sarimukti. The plot of susceptibilities ratio versus coercive force has a great potential to be used as a discriminating tool for determining the source of magnetic minerals.

摘要

从印度尼西亚万隆的杰勒孔和萨拉米图基两个城市固体废物场采集了渗滤液污泥样品。使用 X 射线衍射 (XRD)、扫描电子显微镜配备能量色散 X 射线光谱 (SEM-EDX) 和岩石磁学分析对其磁性矿物学和粒度进行了分析,以区分磁性矿物的来源。SEM-EDX 分析推断渗滤液污泥中的主要磁性矿物是氧化铁。就其形态而言,杰勒孔的颗粒大多呈八面体和角状,与当地土壤中磁性颗粒的一般形状相似。另一方面,萨拉米图基的颗粒主要为不完美的球粒形状,表明是燃烧过程的产物。磁滞参数验证了渗滤液污泥中主要的磁性矿物是低矫顽力亚铁磁性矿物,如磁铁矿 (Fe(3)O(4))。此外,岩石磁学参数的比较表明,杰勒孔土壤样品中的磁性矿物具有更高的磁成土程度,表明超顺磁/超细颗粒的比例高于萨拉米图基土壤样品。磁化率比与矫顽力的关系图具有作为磁性矿物来源的鉴别工具的巨大潜力。

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