Mansell Stephen M, Norman Nicholas C, Russell Christopher A
University of Bristol, School of Chemistry, Bristol, UKBS8 1TS.
Dalton Trans. 2010 Jun 7;39(21):5084-6. doi: 10.1039/c0dt00028k.
The synthesis and structural characterisation of [BPh(bipy)] and [BCl(bipy)] are described both of which contain a direduced bipy ligand (bipy = 2,2'-bipyridyl) and are analogues of the fluorenyl anion; DFT calculations highlight differences in the electronic structure of both species compared to the fluorenyl anion.
描述了[BPh(bipy)]和[BCl(bipy)]的合成及结构表征，二者均含有一个双还原的联吡啶配体（bipy = 2,2'-联吡啶），并且是芴基阴离子的类似物；密度泛函理论计算突出了与芴基阴离子相比这两种物质电子结构的差异。
