一种手性 2,6-双(噁唑啉基)吡啶配体，带有酰胺基团，通过所有镧系元素系列形成同构配合物。
A chiral 2,6-bis(oxazolinyl)pyridine ligand with amide groups to form isomorphous complexes through all the lanthanoid series.
机构信息
Department of Materials and Life Science, Seikei University, 3-3-1 Kichijoji-kitamachi, Musashino, Tokyo, 180-8633, Japan.
出版信息
Inorg Chem. 2010 Jun 7;49(11):4717-9. doi: 10.1021/ic901743q.
PMID:20438091
Abstract
We newly synthesized the chiral pybox ligand, 2,6-bis[(4S)-tert-butylcarbamoyl-2-oxazolin-2-yl]pyridine, whose lanthanoid(III) complexes have formed isomorphous crystals through all the lanthanoid series. The luminescence properties of the Eu(III) complex have been investigated.
摘要
我们新合成了手性 pybox 配体 2,6-双[(4S)-叔丁基氨甲酰基-2-恶唑啉-2-基]吡啶，其镧系（III）配合物通过所有镧系元素系列形成了同构晶体。研究了 Eu(III)配合物的发光性质。
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