Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan.
Dalton Trans. 2009 Aug 21(31):6151-8. doi: 10.1039/b906018a. Epub 2009 Jun 17.
Pt(II) complex of meso-tetrakis(pentafluorophenyl) N-confused porphyrin (1-Pt) efficiently binds Cl(-), Br(-), and I(-) anions at the peripheral N-H, while deprotonation proceeds with F(-), H(2)PO(4)(-), and OH(-) in CH(2)Cl(2) solution; neutral and anionic structures of 1-Pt were characterized by single crystal X-ray diffraction analysis.
具有 N-杂环戊二烯基取代的meso-四(五氟苯基)卟啉 Pt(II)配合物(1-Pt)能够在其外围 N-H 位置有效地结合 Cl(-)、Br(-)和 I(-)阴离子，而在 CH(2)Cl(2)溶液中 F(-)、H(2)PO(4)(-)和 OH(-)的去质子化过程则会发生；通过单晶 X 射线衍射分析对 1-Pt 的中性和阴离子结构进行了表征。
