二聚体纳米胶囊诱导构象变化。
Dimeric nanocapsule induces conformational change.
机构信息
Department of Chemistry, University of Missouri-Columbia, 601 S, College Avenue, Columbia, MO 65211, USA.
出版信息
Chem Commun (Camb). 2010 Feb 28;46(8):1235-7. doi: 10.1039/b921911k. Epub 2010 Jan 15.
DOI:10.1039/b921911k
PMID:20449261
Abstract
An induced cis-trans-trans (rctt) chair to cone structural rearrangement is forced by the addition of a pentacoordinate zinc(II) complex, overcoming thermodynamic and kinetic factors to produce the first phenyl-substituted zinc dimeric nanocapsule.
摘要
一个五元配位锌（II）配合物的加入迫使顺式-反式-反式（rctt）椅到锥形结构重排，克服热力学和动力学因素，生成首例取代的锌二聚纳米胶囊。
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