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基于前所未有的铜介导的二氢罗斯胺氧化反应,用于水样和活细胞中 Cu2+ 的荧光开启检测。

Fluorescence turn-on detection of Cu2+ in water samples and living cells based on the unprecedented copper-mediated dihydrorosamine oxidation reaction.

机构信息

State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, Hunan 410082, PR China.

出版信息

Chem Commun (Camb). 2010 Feb 28;46(8):1311-3. doi: 10.1039/b919531a. Epub 2010 Jan 15.

Abstract

A fluorescence turn-on probe for Cu(2+) based on the novel copper-mediated dihydrorosamine oxidation reaction has been constructed and employed in the detection of Cu(2+) in water, new born calf serum, and living cells, and the new copper-mediated dihydrorosamine oxidation reaction likely proceeds by a copper redox mechanism.

摘要

构建了一种基于新型铜介导的二氢罗斯胺氧化反应的荧光开启探针,并将其用于水、新生小牛血清和活细胞中 Cu(2+)的检测,新型铜介导的二氢罗斯胺氧化反应可能通过铜氧化还原机制进行。

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