双重可控分步超分子互变。
Dual-controllable stepwise supramolecular interconversions.
机构信息
Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science & Technology, Shanghai 200237, PR China.
出版信息
Chem Commun (Camb). 2010 Apr 21;46(15):2587-9. doi: 10.1039/b926323c. Epub 2010 Feb 2.
DOI:10.1039/b926323c
PMID:20449316
Abstract
A new unsymmetric guest compound comprising ferrocene and azobenzene moieties was synthesized and can form a host-guest system with beta-cyclodextrin (beta-CD) complexed. The complexation stoichiometries and sites of the ensembles can be selectively controlled by reversible redox and photoirradiation.
摘要
合成了一种新型不对称的主体化合物，由二茂铁和偶氮苯部分组成，可与β-环糊精（β-CD）形成主客体包合物。通过可逆的氧化还原和光辐照，可以选择性地控制配合物的化学计量比和配位位置。
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