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高发光双环金属铱(III)乙二胺配合物的合成及固态多晶型性与光物理性质的关系。

Highly luminescent bis-cyclometalated iridium(III) ethylenediamine complex: synthesis and correlation between the solid state polymorphism and the photophysical properties.

机构信息

Centro di Eccellenza CEMIF.CAL, LASCAMM CR-INSTM and Laboratorio Regionale Licryl, CNR-INFM, Dipartimento di Chimica, Università della Calabria, 87030 Arcavacata di Rende, Italy.

出版信息

Dalton Trans. 2010 Feb 21;39(7):1709-12. doi: 10.1039/b925471b. Epub 2010 Jan 5.

DOI:10.1039/b925471b
PMID:20449409
Abstract

The solvent induced polymorphism observed in a cyclometalated iridium(iii) ethylenediamine ionic complex is a new tool to modulate and enhance emission in the solid crystalline state.

摘要

溶剂诱导的构象变化在环金属铱(III)乙二胺离子配合物中观察到，这是一种新的工具，可以调节和增强固态晶体中的发射。

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