新型并苯双酰亚胺两亲分子的合成及可控自组装。
Synthesis and controllable self-assembly of a novel coronene bisimide amphiphile.
机构信息
Supramolecular Chemistry Laboratory, New Chemistry Unit, Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Bangalore-560064, India.
出版信息
Org Lett. 2010 Jun 4;12(11):2656-9. doi: 10.1021/ol100864e.
PMID:20450161
Abstract
The synthesis of an amphiphilic coronene bisimide (Amph-CBI) and its self-assembly in THF/water through pi-pi stacking and solvophobic interactions are reported. Spectroscopic and microscopic studies revealed a bilayer like self-assembly of the coronene amphiphile to different kinds of one-dimensional nanostructures, such as nanotubes and nanotapes, which can be controlled by solvent composition.
摘要
本文报道了一种两亲性并苯双酰亚胺（Amph-CBI）的合成及其在 THF/水溶剂中通过π-π堆积和溶剂化作用自组装成双层结构。光谱和显微镜研究表明，这种并苯两亲分子可以通过溶剂组成来控制自组装形成不同种类的一维纳米结构，如纳米管和纳米带。
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