从 Fe（和 Mo）到 Sn 的甲基转移：光化学辐照 (eta(5)-C(5)H(5))M(CO)(n)Me 和 (t)Bu(2)SnH(2) 生成 (eta(5)-C(5)H(5))M(CO)(n)Sn(t)Bu(2)Me (M = Fe, n = 2；M = Mo, n = 3) 配合物。
Methyl transfer from Fe (and Mo) to Sn: formation of (eta(5)-C(5)H(5))M(CO)(n)Sn(t)Bu(2)Me (M = Fe, n = 2; M = Mo, n = 3) complexes from photochemical irradiation of (eta(5)-C(5)H(5))M(CO)(n)Me and (t)Bu(2)SnH(2).
机构信息
Department of Chemistry, University of Texas at El Paso, El Paso, TX 79968-0513, USA.
出版信息
Chem Commun (Camb). 2010 Jul 7;46(25):4586-8. doi: 10.1039/b925851e. Epub 2010 May 11.
DOI:10.1039/b925851e
PMID:20458406
Abstract
Formation of an Sn-CH(3) bond, concomitantly with an Sn-M (M = Fe, Mo), is readily achieved from the photochemical reactions of (t)Bu(2)SnH(2) with (eta(5)-C(5)H(5))M(CO)(n)Me (M = Fe, n = 2; M = Mo, n = 3) via the intermediacy of (eta(5)-C(5)H(5))M(CO)(n)Sn(t)Bu(2)H.
摘要
Sn-CH(3) 键的形成伴随着 Sn-M（M = Fe，Mo）键的形成，这很容易通过（t）Bu（2）SnH（2）与（eta（5）-C（5）H（5））M（CO）（n）Me（M = Fe，n = 2；M = Mo，n = 3）的光化学反应来实现，通过中间体（eta（5）-C（5）H（5））M（CO）（n）Sn（t）Bu（2）H。
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