Chemistry Department, REQUIMTE, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica, Portugal.
Org Biomol Chem. 2010 Jun 28;8(13):2968-74. doi: 10.1039/c001894e. Epub 2010 May 11.
Aziridination and unpredicted homologation reaction of N-sulfonylimines were achieved easily with a very simple, rapid and mild procedure through the use of diazomethane without the presence of any catalyst. The method represents an attractive alternative to metal-catalyzed processes.
通过使用重氮甲烷,在没有任何催化剂的情况下,很容易以非常简单、快速和温和的方法实现 N-磺酰亚胺的氮丙啶化和意外的同系化反应。该方法为金属催化过程提供了一种有吸引力的替代方案。