Department of Chemistry, Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford, OX1 3TA, UK.
Org Biomol Chem. 2010 Jun 28;8(13):3060-3. doi: 10.1039/c003693e. Epub 2010 May 18.
Unprecedented bicyclic methylene aziridines are prepared by rhodium(II)-catalyzed allene aziridination of buta-2,3-dienyl carbamates. Aspects of their NMR and X-ray data are described and a preliminary reactivity profile is given, including overall S(N)V-mode ring-opening with organometallic reagents.
通过铑（II）催化的巴豆-2,3-二烯基氨基甲酸酯的烯丙基氮丙啶化反应，制备了前所未有的双环亚甲基氮丙啶。描述了它们的 NMR 和 X 射线数据的各个方面，并给出了初步的反应性概况，包括与有机金属试剂的总体 S（N）V 模式的开环。
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