亚甲基氮丙啶的合成与应用

Pan Bin, Li Feng, Zhao Yingying

Shandong Peninsula Engineering Research Center of Comprehensive Brine Utilization, Weifang University of Science and Technology Shouguang China

School of Chemistry and Chemical Engineering, Liaoning Normal University 850 Huanghe Road Dalian 116029 China

RSC Adv. 2020 Oct 27;10(64):39304-39322. doi: 10.1039/d0ra07663e. eCollection 2020 Oct 21.

Methyleneaziridines (MAs) are a special subset of aziridines featuring an exocyclic C-C double bond on the three-membered ring. They have found great potential in organic synthesis. In this review, the structural characterization of MAs, synthetic methods, chemical transformations and mechanisms, especially the advances achieved over the past decade are comprehensively summarized.

亚甲基氮杂环丙烷（MAs）是氮杂环丙烷的一个特殊子集，其在三元环上具有一个环外碳 - 碳双键。它们在有机合成中具有巨大潜力。在本综述中，全面总结了MAs的结构表征、合成方法、化学转化及机理，特别是过去十年所取得的进展。