关于Sb3+/O2-离子对的精确键价参数。
On the accurate bond-valence parameters for the Sb3+/O2- ion pair.
作者信息
Sidey Vasyl
机构信息
Department of Chemistry and Research Institute for Physics and Chemistry of Solids, Uzhgorod National University, Pidgirna Street 46, Uzhgorod 88000, Ukraine.
出版信息
Acta Crystallogr B. 2010 Jun;66(Pt 3):307-14. doi: 10.1107/S010876811000892X. Epub 2010 May 6.
PMID:20484801
Abstract
The improved values of the bond-valence parameters for the Sb(3+)/O(2-) ion pair, r(0) = 1.927 A and b = 0.446 A, have been deduced from the crystal structures of the alpha and beta polymorphs of Sb(2)O(3) and from the set of precisely determined complex structures containing [Sb(3+)O(n)] coordination shells.
摘要
Sb(3+)/O(2-)离子对的键价参数改进值，r(0) = 1.927 Å和b = 0.446 Å，是从Sb(2)O(3)的α和β多晶型物的晶体结构以及包含[Sb(3+)O(n)]配位壳层的一组精确测定的复杂结构中推导出来的。
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