三齿配体的铜(II)配合物被一氧化氮还原和配体的三硝化。
Reduction of copper(II) complexes of tripodal ligands by nitric oxide and trinitrosation of the ligands.
机构信息
Department of Chemistry, Indian Institute of Technology-Guwahati, Guwahati, Assam 781039, India.
出版信息
J Am Chem Soc. 2010 Jun 16;132(23):7846-7. doi: 10.1021/ja102279c.
PMID:20491439
Abstract
The copper(II) centers in two copper(II) complexes of tripodal amine ligands, in acetonitrile solvent, upon exposure to nitric oxide have been found to produce a thermally unstable [Cu(II)-NO] intermediate followed by the reduction of copper(II) to copper(I). This reduction resulted in the concomitant trinitrosation of the ligands at their terminal amine centers.
摘要
在乙腈溶剂中，当三齿胺配体的两个铜（II）配合物暴露于一氧化氮时，人们发现其中的铜（II）中心会产生一个热不稳定的[Cu（II）-NO]中间体，随后铜（II）被还原为铜（I）。这种还原导致配体末端胺中心的同时三硝化。
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