A.M. Prokhorov General Physics Institute, Russian Academy of Sciences, ul. Vavilova, 38, 119991, Moscow, Russia.
J Phys Chem B. 2010 Jun 17;114(23):7743-52. doi: 10.1021/jp101657f.
It is shown that water contains defects in the form of heterogeneous optical breakdown centers. Long-living complexes composed of gas and liquid molecules may serve as nuclei for such centers. A new technique for removing dissolved gas from water is developed. It is based on a "helium washing" routine. The structure of helium-washed water is very different from that of water containing dissolved atmospheric gas. It is able to withstand higher optical intensities and temperatures of superheating compared with the nonprocessed ones. The characteristics of plasma spark and values of the breakdown thresholds for processed and nonprocessed samples are given.
研究表明,水中存在不均匀光击穿中心形式的缺陷。由气液分子组成的长寿命复合物可能充当此类中心的核。开发了一种从水中去除溶解气体的新技术。它基于“氦气洗涤”程序。与含有溶解大气气体的水相比,经过氦气洗涤的水的结构有很大的不同。它能够承受更高的光强度和过热温度。给出了等离子体火花的特性和处理与未处理样品的击穿阈值的值。