水中转移氢化：α-氰基和α-硝基取代苯乙酮的对映选择性、催化还原。
Transfer hydrogenation in water: enantioselective, catalytic reduction of alpha-cyano and alpha-nitro substituted acetophenones.
机构信息
Laboratorium für organische Chemie, ETH Zürich, Hönggerberg, Switzerland.
出版信息
Org Lett. 2010 Jul 2;12(13):2893-5. doi: 10.1021/ol1008894.
PMID:20515015
Abstract
Catalytic reduction of alpha-substituted acetophenones under conditions involving asymmetric transfer hydrogenation in water is described. The reaction is conducted in water and open to air, and formic acid is used as reductant.
摘要
描述了在涉及水相不对称转移氢化的条件下催化还原α-取代苯乙酮的方法。该反应在水中进行，并在开放体系中进行，甲酸被用作还原剂。
Zotero 插件