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选择离子流管-质谱法用于干发酵香肠顶空香气化合物的绝对定量。

Selected ion flow tube-mass spectrometry for absolute quantification of aroma compounds in the headspace of dry fermented sausages.

机构信息

Instituto de Agroquímica y Tecnología de Alimentos (CSIC), Apartado 73, 46100 Burjassot, Valencia, Spain.

出版信息

Anal Chem. 2010 Jul 1;82(13):5819-29. doi: 10.1021/ac1009723.

Abstract

The meat industry is interested in rapid control of the sensory quality of meat products. Selected ion flow tube mass spectrometry (SIFT-MS) has been applied to the rapid, real-time quantification of 31 volatile aroma compounds present in the headspace (HS) of dry fermented sausages. Three batches of fermented sausages with different fat contents (10, 20, and 30%) were monitored throughout the processing time. SIFT-MS revealed significant changes in the concentration of all the aroma compounds during the processing time. Moreover, among the various batches of the sausages, significant differences were revealed in their HS concentration of butanal, 2-pentenal, hexanal, 2-butanone, 2,3-butanedione, ethanol, ethyl formate, hexanoic acid, and dimethyl disulfide. In addition, highly volatile compounds were detected and quantified using our real-time SIFT-MS technique that are apparently not generally seen by trace gas extraction and GC techniques.

摘要

肉类行业热衷于快速控制肉类产品的感官质量。选择离子流管质谱(SIFT-MS)已被应用于快速、实时定量分析干发酵香肠顶空(HS)中存在的 31 种挥发性香气化合物。三批脂肪含量不同(10%、20%和 30%)的发酵香肠在整个加工过程中进行了监测。SIFT-MS 揭示了在加工过程中所有香气化合物浓度的显著变化。此外,在不同批次的香肠中,它们的 HS 浓度中丁醛、2-戊烯醛、己醛、2-丁酮、2,3-丁二酮、乙醇、甲酸乙酯、己酸和二甲基二硫都有显著差异。此外,使用我们的实时 SIFT-MS 技术还检测和定量了高度挥发性化合物,这些化合物显然不能通过痕量气体提取和 GC 技术普遍看到。

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