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经 TiO2 纳米粒子负载的氧气和氩气射频等离子体处理的聚酯纤维的性能得到改善。

Improved properties of oxygen and argon RF plasma-activated polyester fabrics loaded with TiO2 nanoparticles.

机构信息

Textile Engineering Department, Faculty of Technology and Metallurgy, University of Belgrade, 11120 Belgrade, Serbia.

出版信息

ACS Appl Mater Interfaces. 2010 Jun;2(6):1700-6. doi: 10.1021/am100209n.

Abstract

The potentials of low-pressure capacitively coupled RF oxygen and argon plasmas for the activation of polyester fibers surface that can enhance the deposition of colloidal TiO(2) nanoparticles were discussed. SEM and XPS analysis confirmed the plasma-induced morphological and chemical changes on the surface of polyester fibers. Oxygen and argon plasma pretreated polyester fabrics loaded with TiO(2) nanoparticles provided maximum reduction of Gram-negative bacteria E. coli and UV blocking. The self-cleaning effects tested on blueberry juice stains and photodegradation of methylene blue in aqueous solution proved excellent photocatalytic activity of TiO(2) nanoparticles deposited onto fiber surface. Although both plasmas significantly contributed to overall improvement of properties of such nanocomposite textile material, oxygen plasma treatment, in particular, enhanced the deposition of colloidal TiO(2) nanoparticles and thus ensured superior effects.

摘要

讨论了低压电容耦合 RF 氧气和氩气等离子体对聚酯纤维表面进行活化的潜力,这可以增强胶体 TiO(2)纳米颗粒的沉积。SEM 和 XPS 分析证实了等离子体诱导聚酯纤维表面的形态和化学变化。用 TiO(2)纳米颗粒负载的经氧气和氩气等离子体预处理的聚酯织物提供了对革兰氏阴性菌大肠杆菌和紫外线阻挡的最大减少。在蓝莓汁污渍上进行的自清洁效果测试和水溶液中亚甲基蓝的光降解证明了沉积在纤维表面的 TiO(2)纳米颗粒具有优异的光催化活性。尽管两种等离子体都显著有助于改善这种纳米复合纺织材料的整体性能,但氧气等离子体处理,特别是增强了胶体 TiO(2)纳米颗粒的沉积,从而确保了更好的效果。

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