通过支撑配体来操纵电子结构：不对称镍串 [Ni(7)(phdptrany)(4)Cl](PF(6)) 线性金属骨架中的电荷非定域模型。
Manipulation of electronic structure via supporting ligands: a charge disproportionate model within the linear metal framework of asymmetric nickel string [Ni(7)(phdptrany)(4)Cl](PF(6)).
机构信息
Department of Chemistry, National Taiwan University, Taipei, 106, Taiwan, ROC.
出版信息
Chem Commun (Camb). 2010 Jul 21;46(27):5018-20. doi: 10.1039/b926315b. Epub 2010 Jun 4.
DOI:10.1039/b926315b
PMID:20526484
Abstract
This paper describes the synthesis and physical properties of an uniquely asymmetric heptanickel string complex exhibiting a charge disproportionate model along the linear nickel framework.
摘要
本文描述了一种独特的不对称七镍链复合物的合成和物理性质，该复合物沿线性镍骨架表现出电荷非比例模型。
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