通过在 3-位或 3,5-位的氧化亲核氢取代反应直接官能化 BODIPY 染料。
Direct functionalization of BODIPY dyes by oxidative nucleophilic hydrogen substitution at the 3- or 3,5-positions.
机构信息
Department of Chemistry, Katholieke Universiteit Leuven, Celestijnenlaan 200f - bus 02404, 3001 Leuven, Belgium.
出版信息
Chem Commun (Camb). 2010 Jul 21;46(27):4908-10. doi: 10.1039/c0cc00568a. Epub 2010 Jun 8.
PMID:20532331
Abstract
BODIPY dyes are shown to be susceptible to oxidative nucleophilic substitution of the alpha-hydrogens, incorporating nitrogen and carbon nucleophiles in a single, high yielding step. The reaction is an excellent alternative to conventional functionalization of this popular fluorophore.
摘要
BODIPY 染料易发生α-氢的氧化亲核取代反应，可在一步反应中高产率地引入氮和碳亲核试剂。该反应是对这种常用荧光团进行传统官能化的极好替代方法。
Zotero 插件