Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, 532 10 Pardubice, Czech Republic.
Magn Reson Chem. 2010 Jul;48(7):562-4. doi: 10.1002/mrc.2608.
The reaction of vanadocene dichloride with sodium arsenate gives Cp(2)V(O(2)AsO(2)H). This compound was identified on the basis of the super-hyperfine coupling observed in the solution EPR spectrum. The effect of substitution was studied on the ring-substituted and ansa-bridged compounds.
二氯二茂钒与砷酸钠反应生成 Cp(2)V(O(2)AsO(2)H)。该化合物是基于在溶液 EPR 光谱中观察到的超超精细耦合而被鉴定的。还研究了取代基对环取代和ansa-桥连化合物的影响。